MATLAB is great for making high-quality figures for publication. It has a pretty steep learning curve, though, if you're used to spreadsheets.
MATLAB's huge advantage for graphing is that everything can be tuned and tweaked with commands and scripts. You only have to fuss over the first graph in a series; once you have everything the way you want it to look, you can use the same formatting script on all your other graphs. Presto, they all look good and they all match.
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